turmeric powders (right: alkalized)

How Turmeric Gets its Color (& How to Make it Turn Red!)

The ‘secret’ behind that yellow dal, yellow rice, or beautifully colored curry? A decent chance that it’s turmeric. A mere teaspoon can help color a sauce or dish and it’s not just used in savory dishes. In some countries it is used in cheeses and butter, to give them a slight yellow hue. And upon closer inspection of your food labels, you might find turmeric (or curcumin, the main colorant) to be present in your popcorn or dessert.

Even though turmeric is often heralded for its possible health benefits we’re mostly interested in this bright (and stable!) colored spice comes from.

Turmeric starts out in the ground

If you use turmeric as a spice, you’ve likely bought it as a bright yellow powder. Turmeric starts out as a mass of roots (rhizome), growing underground, just like ginger and lotus root. The outside of the tuber is yellow/brown and rough, but upon cutting it open though you will find an orange-ish color, some brighter than others. It’s the inside you’re after when harvesting and processing turmeric root for making turmeric powder.

This further processing starts by boiling or steaming the ‘rhizome’. Once cooked sufficiently, they’re dried until they contain about 8-10% moisture. Traditionally this was done using just the sun, though nowadays it is also done industrially. Once cooked and dried, a manufacturer will remove the rough outside of the tuber (polishing). Then it’s a matter of grinding the remainder of the root into a powder. The resulting powder doesn’t just have a bright color but also a distinct flavor and smell.

Color comes from curcumin

So what makes the resulting powder the bright yellow? It’s a group of molecules called curcuminoids which all have a very similar chemical structure. The three most common curcuminoids in turmeric are curcumin, demethoxycurcumin, and bisdemethoxycurcumin. Up to about 6,5% of turmeric is made of curcuminoids and of that, more than half is curcumin. You may sometimes find that this mixture of curcuminoids is sometimes referred to as simply ‘curcumin’.

Curcumin is the main ‘culprit’ for the yellow color of turmeric and is quite a stable molecule in its dry form. As is typical for colored molecules, the curcumin molecule contains several rings and double bonds which are used to ‘capture’ light.

Curcumin (keto form) SOURCE

If you’ve stored turmeric powder for a long (that is, years) period of time, you may have noticed that it barely changes color. And that is correct, dry curcumin, kept out of light, is very stable. Unfortunately though, if you use turmeric for both its color and flavor properties, that might fool you. The color is a lot more stable than the aroma which does decrease over time. Some of those typical turmeric aroma molecules are turmerone, ar-turmerone, and zingiberene (the last is also common in ginger).

Turning turmeric red!

Just like a lot of other natural food colors (e.g. the anthocyanins in red cabbage) curcumin is sensitive to the pH-value of its surroundings. At an alkaline pH (above 7, roughly within the 7-9.5 range) curcumin will turn a dark red color. Even though literature describes the process as ‘spontaneous’, in some of our experiments we did also have to add a little heat to the mix to actually initiate the color change.

This color change is due to a slight change of configuration of the molecule in the 2 oxygen molecules in the middle of the molecule. That slight change will change just how light is absorbed and reflected, causing the powder to change color!

You can make this red turmeric powder at home, we’ve described the process at the bottom of this post.

turmeric powders (right: alkalized)

Non-food uses

To strengthen the power of curcumin, you can extract it from the turmeric. In this form, curcumin is used as a colorant in a wide range of applications, not just food. It can be used to naturally dye clothing for instance (though it’s not too stable over time under the influence of sun light). Also, in India turmeric can be used to make sindoor, the bright red powder worn by married women on their forehead. By mixing slaked lime (which is very alkaline, so not the fruit called lime which is acidic) with the turmeric, it will turn the typical dark red color.

What else is turmeric made of?

Curcuminoids only make up about 5-6,5% of turmeric powder, despite the whole powder seeming yellow. Actually, about 70% of turmeric is made up of carbohydrates. Most plants, and turmeric is simply a ground root, contain a large amount of carbohydrates which make up the structure of the plant. Turmeric powder also still contains water, some fats and proteins and volatile oils.

That turmeric is made up of a mix of components shows well when you try to dissolve turmeric in water. First of all, the majority of the turmeric won’t dissolve. Instead, it will slowly sediment to the bottom of the liquid. What’s interesting though is that several separate layers of sediment form (especially under alkaline conditions). Some components will float, whereas others sink, demonstrating the difference in density.

turmeric in alkaline environment

Experimenting with the color of Turmeric

Prep Time: 5 minutes
Active Time: 10 minutes
Total Time: 15 minutes

Turmeric powder you buy in the store has a bright yellow/orange color to it. Like many other natural food colors, this color is sensitive to the surrounding pH (a measure for acidity/basic environments). Turmeric placed in an alkaline solution will turn bright red! You can simulate this effect yourself by using baking soda, some water, and a microwave!

Materials

  • Turmeric powder
  • Water
  • Baking soda

Tools

  • Microwave
  • Microwave proof glass
  • Microwave proof dish
  • Stirrer or spoons

Instructions

Experiment 1: Making red turmeric powder

This experiment makes bright red turmeric powder. Since you're aiming for a powder, you will only need very little water. You can make as much or as little as you want, simply scale up or scale down the quantities below.

  1. Take your microwave-proof dish and add 2 tbsp of turmeric powder and 1 tsp of baking soda. Use a spoon to mix the powders together.
  2. Add a little water, enough to form a wet paste, but not so much that it easily runs off the plate.
  3. In bursts of 10-30s (max. powder, time, and power depend on your microwave) heat your paste mixture. In between heating cycles, gently mix the mixture to evenly spread it. After a few bursts, you should start to see the mixture turn red. Also, you will see it will dry out. If it dries out before being a nice vibrant red, add a little extra water to make it into a paste again.
  4. Once the paste has turned a dark red and has dried, stop heating. You've now got red turmeric powder!

Experiment 2: Making red turmeric 'juice'

This experiment is very similar to the last one, but instead of making a powder, you'll be making a red liquid.

  1. Take your microwave-proof glass and fill with 0.5 tsp of turmeric powder and 100ml (about 3oz, exact quantities are not important here) of water. Add 2 tsp of baking soda.
  2. Mix the ingredients together using a stirrer.
  3. As for experiment one, heat you mixture in the microwave for 10-30s. Stir in between each heating cycle taking care not to overheat the mixture. Your liquid should start turning red over time with the increasing temperature!

turmeric in alkaline environment

Notes

The color of turmeric is determined by curcumin (and some other curcuminoids). The chemical configuration of curcumin changes when the pH-level changes, especially when it turns more alkaline. However, the change is not immediate, as you noticed, you need some sort of heat to activate the reaction. Likely some sort of activation energy is required for the color change to set in or our baking soda is not sufficiently alkaline to induce the reaction by itself.

Keep in mind that these reactions are mostly reversible. In other words, if you place the red turmeric powder is a more acidic environment (be careful, acids + bases can react quite violently) it will turn back to its original yellow color!

References

Curcumin Chemical Structures: By Ronhjones (Talk) – Own work, Public Domain, link & link

Nelson, Kathryn M et al. “The Essential Medicinal Chemistry of Curcumin.” Journal of medicinal chemistry vol. 60,5 (2017): 1620-1637. doi:10.1021/acs.jmedchem.6b00975, link

Priyadarsini, Kavirayani I. 2014. “The Chemistry of Curcumin: From Extraction to Therapeutic Agent” Molecules 19, no. 12: 20091-20112. https://doi.org/10.3390/molecules191220091, link

Sahdeo Prasad and Bharat B. Aggarwal, Herbal Medicine, Biomolecular and Clinical Aspects, 2nd edition, 2011, Taylor & Francis Group, Chapter 13 Turmeric, the Golden Spice, link

Wikipedia, Curcuminoid, link

Wikipedia, Rhizome, link

Wild Turmeric, DIY: How to Make Sindoor/ Kungumam /KumKum at Home, June-28, 2014, link

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